The full explanation is that the decomp lever is there to manually open one exhaust valve to release compresion and allow the piston to be moved just past TDC on the comp stroke with the kick lever prior to giving it a kick start.
Operating the lever with the motor running will also release compression from the combustion chamber and so the motor stops. It also means that the exhaust valve will bash itself against the decomp lobe until the motor stops and this can be felt as small pulses through the decomp lever.
Using the decomp to stop the bike will wear out the decomp lobe faster than if you use it to start the bike.