100ll is going to be the same where ever you go in the world if it's avgas. That's one thing about aviation, many aspects of it are the same the world over, communication, fuel, etc... That way planes don't fall out of the sky, and people don't fly into each other!!
As far as octance goes, there are two methods, RON or research octane number, and ROZ. I don't know about ROZ. However, I do know that they are different. I believe, that research octane unmbers are arrived at by using a test motor at a set load and then the timing is advanced to the point of engine knock or detonation to determine the octane number. There are numerous articles about octane ratings to be found on the internet, so enjoy reading.
One thing I will point out is that there is a great misconception about high octane fuel. Just because you run high octane fuel doesn't mean that you're going to get any more power out of your motor. In fact, you will get less power, that's basically what Taffy was saying. The reason being is that high octane fuel has a slower flame speed, or burn speed than that of a lower octane fuel at a given compression ratio. And as Taffy also pointed out, one needs to advance timing as well. And, you will also end up with a motor that won't start very well either, especially when it's hot.
And let there be no mistake, LL avgas has a lot of lead in it. You will see a nice grey coating on the outlet of your exhaust pipe in short order after you've been running it. Possible benefits would include better ring sealing, and longer valve/valve seat life as the lead will act as a cushion. That's why there was a change in valve seat engineering when unleaded gas came on the scene many years ago, as the older motors relied on lead for the valves. This change to unleaded fuel was done b/c they found out that spewing lead all over the place was bad.
So, if you are going to be getting free gas, why don't you cut your free avgas with regular unleaded gas to give yourself high enough octane at half the price?